No one can work fresh off the runway looks better than Chloe Sevigny. The risk taking style maven attended the season premiere of HBO’s Big Love wearing a gutsy number from the Rodarte spring ’11 collection. The ornately printed blue and white dress featured cut-out detailing and an outlandish peplum silhouette, but we think the actress seamlessly pulled off this hard to wear style. The brightly hued Christian Louboutin heels and matching lip shade were the perfect compliments to the blue halter dress, and added a bit of personal flair to the look. We love to see starlets showcase their fashion chops on the red carpet and we think this risk paid off.